Elastic Electron Scattering from Methane Molecule in the Energy Range from 50-300 eV

Int J Mol Sci. 2021 Jan 11;22(2):647. doi: 10.3390/ijms22020647.

Abstract

Electron interaction with methane molecule and accurate determination of its elastic cross-section is a demanding task for both experimental and theoretical standpoints and relevant for our better understanding of the processes in Earth's and Solar outer planet atmospheres, the greenhouse effect or in plasma physics applications like vapor deposition, complex plasma-wall interactions and edge plasma regions of Tokamak. Methane can serve as a test molecule for advancing novel electron-molecule collision theories. We present a combined experimental and theoretical study of the elastic electron differential cross-section from methane molecule, as well as integral and momentum transfer cross-sections in the intermediate energy range (50-300 eV). The experimental setup, based on a crossed beam technique, comprising of an electron gun, a single capillary gas needle and detection system with a channeltron is used in the measurements. The absolute values for cross-sections are obtained by relative-flow method, using argon as a reference. Theoretical results are acquired using two approximations: simple sum of individual atomic cross-sections and the other with molecular effect taken into the account.

Keywords: cross-section; elastic scattering; electrons; methane.

MeSH terms

  • Algorithms
  • Electrons*
  • Methane / chemistry*
  • Models, Theoretical*
  • Scattering, Radiation*

Substances

  • Methane