Metal-organic frameworks/alginate composite beads as effective adsorbents for the removal of hexavalent chromium from aqueous solution

Abstract

Industrial waste discharge comprising heavy metals into potable water bodies induces many health hazards. This study investigates the role of metal-organic frameworks (MOFs) doped alginate beads (MOFs@ABs) as potential adsorbents for Cr(VI). Effects of pH, stirring rate, temperature, initial chrome concentration, and particles dosage on Cr(VI) adsorption are studied to evaluate adsorption ability of UiO-66@ABs for Cr(VI) removal from aqueous solution. The adsorption kinetics follows pseudo second order and the equilibrium isotherm is consistent with Langmuir isotherm model. The maximum adsorption capacity of UiO-66@ABs calculated from the model conforms to the experimental results. The desorption experiment of Cr(VI) adsorbed UiO-66@ABs (82%) demonstrates satisfactory regeneration efficiency. Based on our findings and comparative controlled experiments, the superiority of UiO-66@ABs promises their potential application in Cr(VI) removal from wastewater.

Keywords: Adsorption kinetics; Alginate composite; Chromium removal; Metal–organic frameworks.