Syringic acid is a methoxyphenol model compound derived from biomass burning, and its photooxidation processes have important effects on atmospheric chemistry. However, its aqueous-phase photochemistry remains unclear. In this study, we systematically report the photooxidation of syringic acid induced by OH radicals in the aqueous phase. Employing the relative rate technique, the bimolecular rate constant for syringic acid reaction with OH radicals was acquired to be (1.1 ± 0.3) × 1010 M-1 s-1. Notably, colored products were formed as the reaction progressed. Furthermore, the UV-vis and fluorescence spectra confirmed the formation of light-absorbing organic species, and the results agreed well with previous results on atmospheric and natural humic-like substances (HULIS). The photooxidation products were detected by high performance liquid chromatography mass spectrometry (HPLC/MS), and a possible reaction mechanism was proposed. The aqueous-phase reaction of syringic acid would undergo functionalization process forming a hydroxylation product that enhances the degree of oxidation of aqueous secondary organic aerosol (aqSOA), and goes through dimerization process by C-C or C-O coupling of phenoxy radicals which may conduce to the formation of HULIS. These findings suggest that the photooxidation of syringic acid is an important pathway for highly oxygenated phenolic aqSOA formation, providing a secondary source for HULIS in a liquid phase or in deliquescent particles surrounded by a layer of water.
Keywords: Aqueous phase; Biomass burning; Humic-like substances (HULIS); Photooxidation; Syringic acid.
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