A hydrogen-bonded organic framework based on redox-active tri(dithiolylidene)cyclohexanetrione

Kilingaru I Shivakumar; Shin-Ichiro Noro; Yuna Yamaguchi; Yusuke Ishigaki; Akinori Saeki; Kiyonori Takahashi; Takayoshi Nakamura; Ichiro Hisaki

doi:10.1039/d0cc07776c

A hydrogen-bonded organic framework based on redox-active tri(dithiolylidene)cyclohexanetrione

Chem Commun (Camb). 2021 Jan 28;57(9):1157-1160. doi: 10.1039/d0cc07776c. Epub 2021 Jan 7.

Authors

Kilingaru I Shivakumar¹, Shin-Ichiro Noro, Yuna Yamaguchi, Yusuke Ishigaki, Akinori Saeki, Kiyonori Takahashi, Takayoshi Nakamura, Ichiro Hisaki

Affiliation

¹ Research Institute for Electronic Science, Hokkaido University, Sapporo, Hokkaido 001-0020, Japan. tnaka@es.hokudai.ac.jp.

PMID: 33411863
DOI: 10.1039/d0cc07776c

Abstract

Redox-active hexakis(4-carboxyphenyl) tri(dithiolylidene)cyclohexanetrione (CPDC) was synthesized. The CPDC-based porous framework, constructed via anomalistic helical hydrogen-bonding, exhibites permanent porosity and photoconductivity.