Metal-organic frameworks/carbon-based materials for environmental remediation: A state-of-the-art mini-review

Abstract

In recent years, many research groups started to study the combination of metal-organic frameworks (MOFs) with nanocarbon materials, which showed the excellent improved performances than MOFs alone. The addition of carbon materials such as graphene oxides (GOs) and carbon nanotubes (CNTs) into MOFs can improve the physico-chemical properties of parent MOFs with excellent chemical robustness, high mechanical and distinguished electronic thermal robustness. These advantages facilitate the wider applications of MOFs/carbon materials (MOFs-C) in more research fields. This paper is devoted to reviewing the recent studies about the preparation and applications of MOFs-C in environmental remediation. This paper discusses the efficient adsorptive removal of a wide range of pollutants by MOFs-C, including organic contaminants and heavy metals from water as well as VOCs and some other toxic gases from atmospheric environment. Additionally, the catalytic performance of these nanocomposites for photocatalysis and Fenton-like oxidation of water pollutants is discussed in details. Meanwhile, the significant roles of nanocarbons and in-depth mechanisms for improved adsorption or catalysis are summarized. Finally, future perspectives on the development and application of MOFs-C composites for pollution remediation are presented at the end of this paper.

Keywords: Carbon materials; MOFs; Pollution remediation; Porous hybrid composites; VOCs; Water contaminants.