Highly efficient activation of peroxymonosulfate by Co3O4/Bi2WO6 p-n heterojunction composites for the degradation of ciprofloxacin under visible light irradiation

Abstract

Photocatalytic technology assisted via peroxymonosulfate (PMS) has good potential in water treatment. In this study, the Co₃O₄/Bi₂WO₆ composite was constructed via an in-situ calcination process and used to activate PMS for the degradation of ciprofloxacin (CIP) under visible light irradiation. The obtained 5 wt% Co₃O₄/Bi₂WO₆(CBWO-2) can highly effectively remove 86.2% CIP within 5 min visible light irradiation in presence of PMS. The excellent degradation performance of Co₃O₄/Bi₂WO₆/PMS system can be attributed to the synergistic effect between p-n heterojunction and PMS activation. The conduction band and valence band deviation between Co₃O₄ and Bi₂WO₆ were calculated by XPS techniques. Besides, DFT calculations were performed to further confirm the internal structure between Co₃O₄ and Bi₂WO₆. This work not only provides an approach to fabricate heterostructures but also indicated that Co₃O₄/Bi₂WO₆/PMS/Vis system is a potential environment remediation alternative for the efficient removal of recalcitrant organic compounds from wastewaters.

Keywords: Co(3)O(4)/Bi(2)WO(6); Organic pollutants; Peroxymonosulfate; Photocatalyst.