A light-driven diffraction grating incorporating two grating patterns with different pitches atop a photothermal actuator (PTA) has been proposed. It is based on graphene oxide/reduced graphene oxide (GO/rGO) induced via femtosecond laser direct writing (FsLDW). The rGO, its controllable linewidth, and transmission support the formation of grating patterns; its noticeably small coefficient of thermal expansion (CTE), good flexibility, and thermal conductivity enable the fabrication of a PTA consisting of a polydimethylsiloxane layer with a relatively large CTE. Under different intensities of light stimuli, diffraction patterns can be efficiently tailored according to different gratings, which are selectively addressed by incident light beam hinging on the bending of the PTA. This is the first demonstration of combining gratings and PTA, wherein the GO plays the role of a bridge. The light-driven mechanism enables the contactless operation of the proposed device, which can be efficiently induced via FsLDW. The diffraction angle could be changed between 2° and 6° horizontally, and the deviation of side lobes from the main lobe could be altered vertically in a continuous range. The proposed device may provide powerful support for activating dynamic diffraction devices in photothermally contactless schemes.