Structure and Formation Mechanism of Methane Explosion Soot

Baisheng Nie; Chao Peng; Kedi Wang; Longlong Yang

doi:10.1021/acsomega.0c04234

Structure and Formation Mechanism of Methane Explosion Soot

ACS Omega. 2020 Dec 7;5(49):31716-31723. doi: 10.1021/acsomega.0c04234. eCollection 2020 Dec 15.

Authors

Baisheng Nie^{1

2

3}, Chao Peng^{1

2}, Kedi Wang^{1

2}, Longlong Yang⁴

Affiliations

¹ Beijing Key Laboratory for Precision Mining of Intergrown Energy and Resources, China University of Mining & Technology (Beijing), Beijing 100083, China.
² Hebei State Key Laboratory of Mine Disaster Prevention, North China Institute of Science and Technology, Beijing 101601, China.
³ Xinjiang Institute of Engineering, Urumchi 830011, Xinjiang, China.
⁴ China Academy of Building Research, Beijing 100013, China.

Abstract

The bright spot phenomenon during the gas explosion was because of the soot particles of high heat radiation characteristics generated during the explosion process. The formation mechanism of soot and precursor polycyclic aromatic hydrocarbons (PAHs) of the methane explosion was numerically simulated using CHEMKIN-PRO. The methane explosion soot of the CH₄-air premixed gas explosion experiments with volume concentrations of 8% was collected, and the pore size distribution and surface structure of the soot were analyzed by low-pressure nitrogen gas adsorption (LP-N₂GA), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results show that C2 and C3 play an important role in the formation of PAHs in the early stage of the explosion reaction. The LP-N₂GA isotherms demonstrate that the pore type of the soot particles is mostly wedge-shaped, which was verified with SEM observations. The SEM analysis showed that the methane explosion soot is composed of a large number of spherical soot aggregates with diameters between 4 and 50 μm and the pores at the particle surface are well developed, some of the particles exhibit a melt sintering feature. Soot aggregates collide with each other with a chain-branched structure, and the diameters of the majority of the particles are of 100 nm according to TEM images. In addition, graphite-like lattice stripes can be clearly seen inside the particles when magnified to 8 nm. This work will provide the basis for further analysis of soot formation in the gas explosion process.