Study on the Synthesized Rosin Glyceride over LaZSM-5 Zeolite Catalyst Synthesized by the in Situ Method

Xiaoxiao Wang; Fang Guo; Yue Yu; Zhenmin Liu; Yingchun Wang; Hongyan Sun; Xianjun Liu; Yongbing Xue; Xianxian Wei; Shaoqing Guo

doi:10.1021/acsomega.0c03427

Study on the Synthesized Rosin Glyceride over LaZSM-5 Zeolite Catalyst Synthesized by the in Situ Method

ACS Omega. 2020 Dec 7;5(49):31543-31550. doi: 10.1021/acsomega.0c03427. eCollection 2020 Dec 15.

Authors

Xiaoxiao Wang¹, Fang Guo², Yue Yu³, Zhenmin Liu¹, Yingchun Wang¹, Hongyan Sun¹, Xianjun Liu¹, Yongbing Xue¹, Xianxian Wei⁴, Shaoqing Guo⁴

Affiliations

¹ School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, PR China.
² College of Chemistry and Chemical Engineering Jin Zhong University, Yuci 030619, PR China.
³ Lin Yi Institutes of Industrial Technology, Linyi 276000, PR China.
⁴ Taiyuan University of Science and Technology, College of Environment and Safety, Taiyuan 030024, PR China.

Abstract

LaZSM-5 zeolite was synthesized by the in situ method and used as catalysts to catalyze the synthesis of rosin glyceride. As a comparison, ZSM-5 was also synthesized and used as catalysts to catalyze the synthesis of rosin glyceride. The synthesized ZSM-5 and LaZSM-5 zeolite catalysts were characterized and analyzed. The experimental results showed that the in situ synthesis of LaZSM-5 made La into the skeleton of ZSM-5 zeolite and increased the amount of Lewis acid on the LaZSM-5 zeolite. Also, Lewis acid was the key to liquid-phase esterification reaction. Compared with ZSM-5 zeolite, LaZSM-5 zeolite contributed to a higher yield and better stability as a catalyst for the synthesis of rosin glycerides.