It is of great significance to study the porosity and permeability properties of medium and low-rank coal. The porosity and permeability in confining stress experiments were used to simulate the porosity and permeability variations of coal samples under different depth conditions. The pore structure of Baoqing coal samples is greatly affected by the confining pressure, and the pores and micro cracks are more easily compressed. Based on the experimental data of mercury intrusion porosimetry (MIP) and nitrogen adsorption (NA), the pore size distributions (PSDs) of medium and low-rank coals were studied. High mercury intrusion pressure would lead to coal matrix compression. Therefore, the pore volume calculated by MIP data was corrected by NA data. The PSDs characteristics of Jixi (JX) coal and Baoqing (BQ) coal samples are obtained from the revised pore volume, and the dominant pores of medium and low-rank coals are obtained. The results show that JX coal has higher spatial heterogeneity, connectivity and pore autocorrelation. Micro fractures have an influence on the autocorrelation and heterogeneity of coal samples, especially for BQ coal samples.