Electrocatalytic degradation of humic acid using particle electrodes of activated carbon loaded with metallic cobalt

Abstract

A column granular electrode loaded with metallic cobalt was prepared using powder activated carbon (namely Co/AC) and used in a continuous electrochemical reactor to degrade humic acid (HA). The results of XRD indicated that the form of catalyst prepared at 600 °C for 4 h mainly consisted of Co⁰, whereas it consisted of CoO when prepared at 450-500 °C for 4 h. The Co⁰ possessed better catalytic effects in the degradation of HA than CoO. When C₀ of HA was 200 mg L^-1, the C/C₀ approached 0.06-0.12 under 0.1 A, pH of 7.0, 0.01 M Na₂SO₄, and 20 min of hydraulic retention time (HRT). The current, HRT, initial pH, electrolyte type and concentration influenced the degradation of HA. The ESR signals indicated that both H∗ and OH were catalytically generated by Co/AC electrode. Compared to AC electrodes, the Co/AC electrodes showed a faster reaction Tafel slope (68 mV dec^-1) and larger electrochemical double-layer capacitance (C_dl = 1.93 mF cm^-2). The degradation and removal of HA was achieved by both the electro-oxidation and electro-reduction in the Co/AC electrode system.

Keywords: Activated carbon; Cobalt; Electro-oxidation; Humic acid; Particle electrodes.