The degradation dynamics and rapid detection of thiacloprid and its degradation products in water and soil by UHPLC-QTOF-MS

Abstract

Thiacloprid is a neonicotinoid insecticide used to control sucking and chewing insects of fruits and vegetables. Hydrolysis, photolysis of thiacloprid in aqueous solutions, and soil degradation of three typical types of soil in China were studied. UHPLC-QTOF/MS was used to acquire high-resolution mass spectrometry information of thiacloprid's degradation products in water and soil samples, and the UNIFI platform with integrated data processing function was used to find and identify degradation products. The degradation kinetics of thiacloprid was determined. Six transformation products (M271, M287, M269, M295, M279, M267) were found after the data processing workflow in the UNIFI platform by using the raw MS^E data. The structure of putative transformation products can be inferred based on the accurate mass of fragment ions and the automated spectral interpretation tools in the UNIFI platform. The structure of M271 was validated to be thiacloprid amide by comparing the ESI-MS² fragment ions in soil samples and thiacloprid amide standard. The TrendPlot function of UNIFI was used to demonstrate the kinetics of the transformation products. Reduction, hydrolysis, oxidation are the main reactions of thiacloprid in three tested soil in China and buffer solutions. This study provided a reference for the rapid identification of the transformation products of other pesticides in specific environmental conditions.

Keywords: Degradation products; Hydrolysis; Photolysis; Soil degradation; Thiacloprid.