Iron-based persulfate activation process for environmental decontamination in water and soil

Abstract

Sulfate radical based advanced oxidation processes have been extensively studied for the degradation of environmental contaminants. Iron-based materials such as ferrous, ferric, ZVI, iron oxides, sulfides etc., and various natural iron minerals have been explored for activating persulfate to generate sulfate radicals. In this review, an overview of different iron activated persulfate systems and their application in the removal of organic pollutants and metals in water and soil are summarised. The chemistry behind the activation of persulfate by homogenous and heterogeneous iron-based materials with/without the assistance of electrochemical techniques are also discussed. Besides, the soil decontamination by iron persulfate system and a brief discussion on the ability of the persulfate system to reduce metals presence in wastewater are also summarised. Finally, future research prospects, believed to be useful for all researchers in this field, based on up to date research progress is also given.

Keywords: Activation; Electrochemical; Heterogeneous; Homogeneous; Iron; Persulfate; Soil decontamination.