Outstanding performance of ZnS/TiO2 for the urgent disposal of liquid mercury leakage indoors: Novel support effect, reaction mechanism and kinetics

Abstract

Effectively weakening the bond strength of Zn-S in S-Zn-S on ZnS is of great significance to the improvement of its performance for the urgent disposal of liquid Hg⁰ leakage indoors. In this work, ZnS was loaded on three common supports (i.e., TiO₂, SiO₂, and Al₂O₃) to further improve its performance for capturing high concentrations of Hg⁰ indoors. After being loaded on TiO₂, the S-Zn-O bond was present on ZnS, and the bond strength of Zn-S in S-Zn-O was significantly weaker than that in S-Zn-S because Zn²⁺ preferred to O^2- than S^2-. Hence, physically adsorbed Hg⁰ was much easier to bond with S in S-Zn-O than that in S-Zn-S to form HgS. Therefore, TiO₂ showed a novel support effect on ZnS for Hg⁰ capture, and the Hg⁰ capture performance of ZnS/TiO₂ was greatly better than those of ZnS, ZnS/SiO₂, and ZnS/Al₂O₃. Moreover, the promotion mechanism of ZnO loading on Hg⁰ adsorption onto TiO₂-S was discovered after comparing the Hg⁰ adsorption kinetic parameters of TiO₂-S and ZnS/TiO₂. The promotion of ZnO loading was primarily related to the notable increase in the content of S^2- that can bond with physically adsorbed Hg⁰, which predominantly resulted from the strong interaction of ZnO/TiO₂ with H₂S.

Keywords: Adsorption kinetics; Hg(0) capture; Liquid Hg(0) leakage indoors; Novel support effect; ZnS/TiO(2).