ZnO Nanoparticles for Photocatalytic Application in Alkali-Activated Materials

Molecules. 2020 Nov 25;25(23):5519. doi: 10.3390/molecules25235519.

Abstract

This paper reports an Alkali-Activated Materials (AAM) using two different precursors, metakaolin and a metallurgical slag with photocatalytic zinc oxide nanoparticles, as novel photocatalytic composites. The photodegradation performance of the composites using methylene blue (MB) dye as a wastewater model was investigated by ultraviolet radiations (UV-vis) spectroscopy. Adsorption in dark conditions and photodegradation under UV irradiation are the mechanisms for removing MB dye. The pseudo-first-order kinetic and pseudo-second-order kinetic models were employed, and the experimental data agreed with the pseudo-second-order model in both cases with UV and without UV irradiations. As new photocatalytic materials, these composites offer an alternative for environmental applications.

Keywords: X-ray diffraction; chemical synthesis; composites; electron microscopy; photocatalytic properties.

MeSH terms

  • Adsorption
  • Algorithms
  • Alkalies / chemistry*
  • Catalysis
  • Kinetics
  • Models, Chemical
  • Nanoparticles / chemistry*
  • Nanoparticles / ultrastructure
  • Photochemical Processes*
  • X-Ray Diffraction
  • Zinc Oxide / chemistry*

Substances

  • Alkalies
  • Zinc Oxide