Self-Assembly of a Redox Active, Metallosupramolecular [Pd3 L6 ]6+ Complex Using a Rotationally Flexible Ferrocene Ligand

Abstract

A new ferrocene-containing [Pd₃ (L_4EFc )₆ ]⁶⁺ (X^- )₆ (C ⋅ BF₄ and C ⋅ SbF₆ where X=BF₄ ^- or SbF₆ ^- ) self-assembled double-walled triangle has been synthesized from the known, rotationally flexible, 1,1'-bis(4-pyridylethynyl)ferrocene ligand (L_4EFc ), and characterized by ¹ H, ¹³ C and diffusion ordered (DOSY) NMR spectroscopies, high-resolution electrospray ionization mass spectrometry (HR-ESI-MS), X-ray crystallography and cyclic voltammetry (CV). The molecular structures confirmed that double-walled triangle cage systems (C ⋅ BF₄ and C ⋅ SbF₆ ) were generated. C ⋅ BF₄ was shown to interact with the anionic guest, p-toluenesulfonate. CV experiments revealed that the triangles were redox active, however addition of the guest did not influence the redox potentials.

Keywords: ferrocene; metallosupramolecular; palladium(II); redox-active; self-assembly.