Step-Economical Synthesis of Conjugated Polymer Materials Composed of Three Components: Donor, Acceptor, and π Units

Abstract

Conjugated polymers have immense potential for their use as semiconducting materials in organic optoelectronic devices. The improvement of synthetic methods for conjugated polymers is important for the practical application of conjugated polymers. For mass production, synthetic methods must be developed by considering the concerns regarding cost and environment. Reduction in the number of synthetic steps is an efficient approach to address these concerns. The utilization of direct CH functionalization is a reasonable strategy in monomer and polymer syntheses, because the prefunctionalization steps for CC bond formation can be eliminated. This review summarizes the recent developments in the efficient syntheses of conjugated polymers as well as their monomers via direct arylation (CH/CX coupling) and cross-dehydrogenative coupling (CH/CH coupling) reactions.

Keywords: conjugated polymers; dehydrogenative coupling; direct arylation; polycondensation; semiconducting materials.