Perovskite semiconductor nanocrystals have emerged as an excellent family of materials for optoelectronic applications, where biexciton interaction is essential for optical gain generation and quantum light emission. However, the strength of biexciton interaction remains highly controversial due to the entangled spectral features of the exciton- and biexciton-related transitions in conventional measurement approaches. Here, we tackle the limitation by using polarization-dependent two-dimensional electronic spectroscopy and quantify the excitation energy-dependent biexciton binding energy at cryogenic temperatures. The biexciton binding energy increases with excitation energy, which can be modeled as a near inverse-square size dependence in the effective mass approximation considering the quantum confinement effect. The spectral line width for the exciton-biexciton transition is much broader than that for the ground state to exciton transition, suggesting weakly correlated broadening between these transitions. These inhomogeneity effects should be carefully considered for the future demonstration of optoelectronic applications relying on coherent exciton-biexciton interactions.