Adsorption characteristics and mechanisms of Pb2+ and Cd2+ by a new agricultural waste-Caragana korshinskii biomass derived biochar

Abstract

In order to explore the comprehensive utilisation and recycling technology of Caragana korshinskii resources, a new agricultural biomass waste, 15 kinds of Caragana korshinskii biochar (CB) were prepared by controlling the pyrolysis temperature and time at the anaerobic environment. Moreover, we pay more attention to deriving the adsorption mechanisms and exploring the difference in adsorption characteristics of Pb²⁺ and Cd²⁺. The optimal preparation conditions and the batch adsorption experiments were evaluated, and the adsorption characteristics and mechanisms were discussed using 8 theoretical adsorption models and multiple characterisation methods. The results showed that the CB prepared at 650 °C for 3 h presented the best performance. The Langmuir and Freundlich models can well simulate the isotherm adsorption process of CB for Pb²⁺ and Cd²⁺, respectively. The adsorption kinetics of CB for Pb²⁺ and Cd²⁺ were best fitted by the pseudo-second-order model. The adsorption equilibrium for Pb²⁺ and Cd²⁺ was reached within 3 h, and their maximum adsorption capacity reached 220.94 mg g^-1 and 42.43 mg g^-1, respectively. In addition, the best addition amount was 3 g L^-1 and 2.2 g L^-1 for Pb²⁺ and Cd²⁺, respectively. The optimum pH range was 3-6 for Pb²⁺ and 6-7.5 for Cd²⁺. The adsorption mechanisms of CB for Pb²⁺ and Cd²⁺ were physicochemical composite adsorption processes, mainly including physical sorption on surface sites, intraparticle diffusion, electrostatic adsorption, ion/ligand exchange, cationic-π interactions, surface complexation and precipitation. Furthermore, the ash of CB also presented a positive effect on the adsorption of Pb²⁺. Compared with other cellulose- and lignin-based biomass materials, CB showed low cost and efficient performance without complicated modification conditions. Therefore, this study demonstrates that CB is a promising raw material in water pollution control to immobilise heavy metals.

Keywords: Adsorption characteristics; Cadmium (Cd2+); Caragana korshinskii biochar; Lead (Pb2+); Mechanisms.