In this approach, we present an efficient topology and geometry optimization of triply periodic minimal surfaces (TPMS) based porous shell structures, which can be represented, analyzed, optimized and stored directly using functions. The proposed framework is directly executed on functions instead of remeshing (tetrahedral/hexahedral), and this framework substantially improves the controllability and efficiency. Specifically, a valid TPMS-based porous shell structure is first constructed by function expressions. The porous shell permits continuous and smooth changes of geometry (shell thickness) and topology (porous period). The porous structures also inherit several of the advantageous properties of TPMS, such as smoothness, full connectivity (no closed hollows), and high controllability. Then, the problem of filling an object's interior region with porous shell can be formulated into a constraint optimization problem with two control parameter functions. Finally, an efficient topology and geometry optimization scheme is presented to obtain optimized scale-varying porous shell structures. In contrast to traditional heuristic methods for TPMS, our work directly optimize both the topology and geometry of TPMS-based structures. Various experiments have shown that our proposed porous structures have obvious advantages in terms of efficiency and effectiveness.