Oxygen Vacancy Engineering in Titanium Dioxide for Sodium Storage

Abstract

Titanium dioxide (TiO₂ ) is a promising anode material for sodium-ion batteries (SIBs) due to its low cost, natural abundance, nontoxicity, and excellent electrochemical stability. Oxygen vacancies, the most common point defects in TiO₂ , can dramatically influence the physical and chemical properties of TiO₂ , including band structure, crystal structure and adsorption properties. Recent studies have demonstrated that oxygen-deficient TiO₂ can significantly enhance sodium storage performance. Considering the importance of oxygen vacancies in modifying the properties of TiO₂ , the structural properties, common synthesis strategies, characterization techniques, as well as the contribution of oxygen-deficient TiO₂ on initial Coulombic efficiency, cyclic stability, rate performance for sodium storage are comprehensively described in this review. Finally, some perspectives on the challenge and future opportunities for the development of oxygen-deficient TiO₂ are proposed.

Keywords: TiO2; defects; electrochemical energy storage; oxygen vacancy; sodium-ion batteries.