The kinetics of thermal degradation of β-chitin extracted from Dosidicus gigas squid pen, was studied at normal conditions as well as after being subjected to the action of high-pressure impact of 9.7 GPa. The integral iso-conversional procedure of Kissinger-Akahira-Sunose (KAS) recommended by the ICTAC kinetics committee was applied to the non-isothermal data obtained from thermogravimetry (TGA). Lifetimes were predicted without assumption of any reaction model. Heating rates of β = 10, 15, 20 and 25 °C/min under nitrogen atmosphere were used from room temperature to 1300 °C. A comparative study with α-chitin was performed. All the samples were structurally and chemically characterized by several techniques. The extracted β-chitin was found to be in the monohydrate form; while with the action of high-pressure impact, it was transformed into β-chitin dehydrate showing slightly higher stability. Reliable prediction for lifetimes considering working temperatures over 425 K was found for α and β-chitin.
Keywords: Chitin (PubChem CID: 6857375); Lifetime; Non-isothermal kinetics; Shock compression; Thermal degradation; α-chitin; β-chitin.
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