Intramolecular aryl-aryl coupling via C-F bond activation tolerant towards C-I functionality

Ann-Kristin Steiner; Mikhail Feofanov; Konstantin Amsharov

doi:10.1039/d0cc06035f

Intramolecular aryl-aryl coupling via C-F bond activation tolerant towards C-I functionality

Chem Commun (Camb). 2020 Nov 19;56(92):14377-14380. doi: 10.1039/d0cc06035f.

Authors

Ann-Kristin Steiner¹, Mikhail Feofanov, Konstantin Amsharov

Affiliation

¹ Institute of Organic Chemistry II, University Erlangen-Nuremberg, Nikolaus-Fiebiger-Str. 10, Erlangen 91058, Germany. konstantin.amsharov@chemie.uni-halle.de.

PMID: 33140779
DOI: 10.1039/d0cc06035f

Abstract

Herein we report a transition-metal free activation of a particularly stable aromatic carbon-fluorine bond allowing intramolecular aryl-aryl coupling which is orthogonal to carbon-iodine functionality.