Chemical Profile and Use of the Peat as an Adsorbent for Extraction of Volatile Compounds from Leaves of Geranium (Pelargonium graveolens L' Herit)

Molecules. 2020 Oct 24;25(21):4923. doi: 10.3390/molecules25214923.

Abstract

Volatile organic compounds (VOCs) from leaves of geranium (Pelargonium graveolens L' Herit) were extracted by dynamic headspace using Porapak Q (HSD-P) as adsorbent and peat, a novel adsorbent in the extraction of plant volatiles, analyzed by gas chromatography-mass spectrometry (GC/MS) and gas chromatography-flame ionization (GC/FID), and the results were compared with those obtained by hydrodistillation (HD). The yield volatiles changed with the extraction method. HD was more efficient for extracting linalool (11.19%) and citronellyl formate (9.41%). Citronellol (28.06%), geraniol (38.26%) and 6,9-guaiadiene (9.55%) and geranyl tiglate (8.21%) were the major components identified by dynamic headspace using peat (HSD-T), while citronellol (16.88%), geraniol (13.63%), 6,9-guaiadiene (16.98%) and citronellyl formate (6.95%) were identified by dynamic headspace using Porapak Q (HSD-P). Furthermore, this work showed, for the first time, that in natura peat is useful to extract VOCs from leaves of geranium.

Keywords: GC/MS; Pelargonium graveolens; peat; porapak Q; volatile organic compounds.

MeSH terms

  • Acyclic Monoterpenes / analysis
  • Acyclic Monoterpenes / isolation & purification
  • Adsorption
  • Crotonates / analysis
  • Crotonates / isolation & purification
  • Gas Chromatography-Mass Spectrometry
  • Geranium / chemistry*
  • Hemiterpenes / analysis
  • Hemiterpenes / isolation & purification
  • Monoterpenes / analysis
  • Monoterpenes / isolation & purification
  • Oils, Volatile / chemistry*
  • Plant Extracts / analysis
  • Plant Extracts / isolation & purification*
  • Plant Leaves / chemistry*
  • Porosity
  • Soil / chemistry*
  • Surface Properties
  • Volatile Organic Compounds / analysis
  • Volatile Organic Compounds / isolation & purification*

Substances

  • Acyclic Monoterpenes
  • Crotonates
  • Hemiterpenes
  • Monoterpenes
  • Oils, Volatile
  • Plant Extracts
  • Soil
  • Volatile Organic Compounds
  • citronellyl formate
  • linalool
  • tiglic acid
  • geraniol
  • citronellol