Heavy metal microextraction and determination in daily used water is accurately achieved by applying nano-clay as an extractor. The conditions for adsorption/elution of Cu(ii), Cd(ii) and Pb(ii) were investigated by adjusting the pH of samples, sample volume and the type of eluent. The nano-clay showed superior efficiency for microextraction of Cu(ii), Cd(ii) and Pb(ii) at pH 2 using 2 mL of nitric acid (1 M) as the eluent. The microextraction procedure showed high recovery% by changing the sample volume from 15 mL to 70 mL. The preconcentration factor was found to be 37.5. The LOD and LOQ were 1.8, 1.3, and 1.9 μg L-1 and 5.3, 3.9, and 5.7 μg L-1 for Cu(ii), Cd(ii) and Pb(ii) respectively. The addition/recovery from different water samples showed recovery% in the range 88-105 which confirms the efficiency and the accuracy of the developed solid phase microextraction using nano-clay for enrichment of Cu(ii), Cd(ii) and Pb(ii).