Enhanced Activity of Hierarchical Nanostructural Birnessite-MnO2-Based Materials Deposited onto Nickel Foam for Efficient Supercapacitor Electrodes

Shang-Chao Hung; Yi-Rong Chou; Cheng-Di Dong; Kuang-Chung Tsai; Wein-Duo Yang

doi:10.3390/nano10101933

Enhanced Activity of Hierarchical Nanostructural Birnessite-MnO₂-Based Materials Deposited onto Nickel Foam for Efficient Supercapacitor Electrodes

Nanomaterials (Basel). 2020 Sep 27;10(10):1933. doi: 10.3390/nano10101933.

Authors

Shang-Chao Hung^{1

2}, Yi-Rong Chou³, Cheng-Di Dong⁴, Kuang-Chung Tsai⁵, Wein-Duo Yang³

Affiliations

¹ Fuzhou Polytechnic, Fuzhou 350108, China.
² Intelligent Technology Research Centre, Fuzhou 350108, China.
³ Department of Chemical and Materials Engineering, National Kaohsiung University of Science and Technology, Kaohsiung 80778, Taiwan.
⁴ Department of Marine Environmental Engineering, National Kaohsiung University of Science and Technology, Kaohsiung 81157, Taiwan.
⁵ Department of Safety, Health and Environmental Engineering, National Kaohsiung University of Science and Technology, Kaohsiung 82445, Taiwan.

Abstract

Hierarchical porous birnessite-MnO₂-based nanostructure composite materials were prepared on a nickel foam substrate by a successive ionic layer adsorption and reaction method (SILAR). Following composition with reduced graphene oxide (rGO) and multiwall carbon nanotubes (MWCNTs), the as-obtained MnO₂, MnO₂/rGO and MnO₂/rGO-MWCNT materials exhibited pore size distributions of 2-8 nm, 5-15 nm and 2-75 nm, respectively. For the MnO₂/rGO-MWCNT material in particular, the addition of MWCNT and rGO enhanced the superb distribution of micropores, mesopores and macropores and greatly improved the electrochemical performance. The as-obtained MnO₂/rGO-MWCNT/NF electrode showed a specific capacitance that reached as high as 416 F·g^-1 at 1 A·g^-1 in 1 M Na₂SO₄ aqueous electrolyte and also an excellent rate capability and high cycling stability, with a capacitance retention of 85.6% after 10,000 cycles. Electrochemical impedance spectroscopy (EIS) analyses showed a low resistance charge transfer resistance for the as-prepared MnO₂/rGO-MWCNT/NF nanostructures. Therefore, MnO₂/rGO-MWCNT/NF composites were successfully synthesized and displayed enhanced electrochemical performance as potential electrode materials for supercapacitors.

Keywords: birnessite-MnO2; electrochemical performance; hierarchical; specific capacitance.

Grants and funding

MOST-106-2221-E-151-040/Ministry of Science and Technology of Taiwan