KOH-Activated Geopolymer Microspheres Recycle Co(II) with Higher Adsorption Capacity than NaOH-Activated Ones

Qiaoqiao Su; Liang Deng; Quan Ye; Yan He; Xuemin Cui

doi:10.1021/acsomega.0c03158

KOH-Activated Geopolymer Microspheres Recycle Co(II) with Higher Adsorption Capacity than NaOH-Activated Ones

ACS Omega. 2020 Sep 10;5(37):23898-23908. doi: 10.1021/acsomega.0c03158. eCollection 2020 Sep 22.

Authors

Qiaoqiao Su¹, Liang Deng¹, Quan Ye¹, Yan He¹, Xuemin Cui¹

Affiliation

¹ School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning 530004, China.

Abstract

A new type of absorbent with high efficiency was synthesized by KOH-activated slag-based geopolymer microspheres (K-SGM), which exhibited higher adsorption capacities for recycling Co(II) (Q _e,K-SGM = 192.31 mg/g, Q _e,Na-SGM = 91.21 mg/g) than NaOH-activated ones (Na-SGM). During the Co(II) adsorption process, these two kinds of geopolymeric adsorbents could be combined with heavy metal ions to optimize each other and form heavy metal-grown aid adsorbents. The morphology of Na-SGM and K-SGM was different which varied from coarse pores to nanonetwork or nanosheets after Co(II) adsorption, and the Brunauer-Emmett-Teller (BET) surface areas of Na-SGM (10.46 m²/g) and K-SGM (22.96 m²/g) increased to 117.38 and 228.73 m²/g after Co(II) adsorption, respectively. The BET surface area of K-SGM is twice that of Na-SGM whether before or after Co(II) ion adsorption. The hydrated ionic radius of K and Na, the alkalinity degree of K⁺ and Na⁺, the electronegativity of Na-SGM and K-SGM surface, the BET surface area and Fourier transform infrared changes of CO₃ ^2- and OH before and after Co(II) adsorption, and X-ray photoelectron spectroscopy analysis like the relative content of geopolymer gel and bridging oxygen bonds in the Na-SGM and K-SGM are the fundamental reasons for the obvious differences in Co(II) adsorption between Na-SGM and K-SGM.