Tuning morphology, composition and oxygen reduction reaction (ORR) catalytic performance of manganese oxide particles fabricated by γ-radiation induced synthesis

Abstract

A γ-radiation induced synthesis method is used to fabricate manganese oxide catalysts through both reduction and oxidation routes. It is shown that the morphology, composition and electrochemical performance of the produced manganese oxide particles can be tuned by altering the redox conditions. The catalysts prepared via radiolytic oxidation have a hollow spherical morphology, possess γ-MnO₂ structure and show high catalytic activity for the complete four-electron reaction pathway of the oxygen reduction reaction (ORR) in alkaline electrolyte. Meanwhile, the catalysts synthesized via radiolytic reduction possess a rod-like morphology with a Mn₃O₄ bulk structure and favour the incomplete two-electron reaction pathway for ORR. The high catalytic activity of the manganese oxide synthesized via the oxidation route can be attributed to high electrochemical surface area and increased amount of Mn³⁺ on the surface as compared to those in the sample obtained via the reduction route.

Keywords: 4-electron transfer; MnOx nanoparticles; ORR; γ-radiation induced synthesis.