Effects of caprolactam content on curdlan-based food packaging film and detection by infrared spectroscopy

Abstract

In this study, we report a rapid statistical approach used in determining the caprolactam (CPL) content in curdlan packaging films, which is based on the spectral data observed in the near-infrared (NIR) and Mid-infrared (MIR) regions. At the first stage of the study, the CPL content was added into the curdlan films prepared by controlling the concentration, and then the effect of the CPL concentration on the measured mechanical properties of the produced films were evaluated. At the next stage, the NIR and MIR spectra of the curdlan films with different CPL concentrations were recorded by using the FT-NIR and FT-IR spectroscopy technique, and the spectral data to be used in the regression models in our quantitative analyses were carefully selected. It was observed that the curdlan film with 5% CPL exhibited the best mechanical properties. The obtained best correlation parameters which are used in evaluation of CPL content through the observed NIR and MIR spectral data are Rp = 0.9552, RMSEP = 1.2506 (NIR); Rp = 0.9092 and RMSEP = 1.9136 (MIR), respectively. These optimal values support the expectation that our statistical approach based on NIR and MIR data can provide a rapid, accurate and nondestructive way of determining CPL content in curdlan packaging films.

Keywords: Caprolactam; Curdlan films; Determination; Mid-infrared spectroscopy; Near-infrared spectroscopy.