The present work deals with the photocatalytic degradation of p-nitrophenol as it is a United States Environmental Protection Agency-listed priority pollutant and has adverse environmental and health effects. To eradicate the detrimental environmental impact of p-nitrophenol, the biologically synthesized ZnO nanoparticles were used as a photocatalyst. The degradation of p-nitrophenol was confirmed by decreasing the absorbance value at a characteristic wavelength of 317 nm using the UV-vis spectrophotometer. Reaction parameters such as ZnO photocatalyst concentration of 0.1 g/L at pH 11 in the presence of H2O2 (5 mM) were found to be optimum conditions for p-nitrophenol degradation. The photocatalytic degradation was slowly enhanced in the presence of H2O2 as an electron acceptor. The kinetics of nitrophenol degradation was studied, which follows the pseudo-first-order reaction. The photocatalytic degradation of p-nitrophenol was characterized by using total organic carbon, chemical oxygen demand, and high-performance liquid chromatography analyses. This method is found to be effective as it is environmentally friendly, free of toxic chemicals.
Keywords: Biosynthesis; Photocatalytic degradation; UV irradiation; ZnO nanoparticles; p-Nitrophenol.