Superadsorbents for Strontium and Cesium Removal Enriched in Amidoxime by a Homo-IPN Strategy Connected with Porous Silica Texture

Ecaterina Stela Dragan; Doina Humelnicu; Maria Ignat; Cristian Dragos Varganici

doi:10.1021/acsami.0c10983

Superadsorbents for Strontium and Cesium Removal Enriched in Amidoxime by a Homo-IPN Strategy Connected with Porous Silica Texture

ACS Appl Mater Interfaces. 2020 Oct 7;12(40):44622-44638. doi: 10.1021/acsami.0c10983. Epub 2020 Sep 27.

Authors

Ecaterina Stela Dragan¹, Doina Humelnicu², Maria Ignat², Cristian Dragos Varganici¹

Affiliations

¹ "Petru Poni" Institute of Macromolecular Chemistry, Grigore Ghica Voda Alley 41 A, Iasi 700487, Romania.
² Faculty of Chemistry, "Al. I. Cuza" University of Iasi, Carol I Bd. 11, 700506 Iasi, Romania.

PMID: 32935537
DOI: 10.1021/acsami.0c10983

Abstract

In light of the fact that two with good compatibility are better than one, the homo-interpenetrating polymer network (IPN) strategy was used in this work to design novel amidoxime (AOX)-interpenetrating networks into porous silica (PSi) with the final aim to enhance the sorption performances of composite sorbents toward Cs⁺ and Sr²⁺. To achieve this goal, first, a homo-IPN of poly(acrylonitrile) (PAN) was constructed inside the channels of two kinds of porous silica, one mesoporous (PSi1) and one macroporous (PSi2), the textural properties of silica being exploited in controlling the sorption performances of the composites. The novel composites were fully characterized by thermogravimetric analysis (TGA), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and the nitrogen sorption/desorption isotherms (Brunauer-Emmett-Teller (BET) analysis). The sorption properties of the PSi1/AOX and PSi2/AOX composite sorbents for Sr²⁺ and Cs⁺ were investigated in the batch mode to determine the effect of solution pH, contact time, initial metal ion concentration, temperature, and the presence of competitive ions on the adsorption performances. The fast kinetics of sorption was supported by the fact that ∼80% of Sr²⁺ and ∼65% of Cs⁺ were adsorbed in the first 30 min, the kinetic data being better described by the pseudo-second-order kinetic model. The experimental isotherms were well fitted by the Langmuir and Sips isotherm models. The superadsorption of Sr²⁺ and Cs⁺ is demonstrated by the values of the maximum sorption capacity of the best sorbent constructed with mesoporous silica (PSi1/IPN-AOX), which were 344.23 mg Cs⁺/g and 360.23 mg Sr²⁺/g. The sorption process was spontaneous and endothermic for both metal ions. The presence of interfering cations (Na⁺, K⁺, Ca²⁺, and Mg²⁺), at a concentration of 10^-2 M, only slightly influenced the sorption capacity for the main cation. The composite sorbents were still highly efficient after five sorption/desorption cycles.

Keywords: adsorption; amidoxime; cesium; homo-IPN; porous silica; strontium.