Dye removal by activated carbon produced from Agave americana fibers: stochastic isotherm and fractal kinetic studies

Abstract

The present work investigates the use of Agave americana fibers (AGF) as a precursor for activated carbon (AC) preparation via chemical activation using phosphoric acid (H₃PO₄), and the study of the influence of the preparation conditions on the adsorption capacity of the prepared AC toward Alpacide Yellow (AY). The preparation experiments have been conducted at different impregnation ratios: acid/AGF (20 g/1 g, 30 g/1 g, and 40 g/1 g) with varied impregnation times (2 h, 4 h, and 6 h) and at different carbonization temperatures (200 °C, 400 °C, and 600 °C). The impregnation ratio of 40 g/1 g, the impregnation time of 6 h, and the carbonization temperature of 400 °C were selected as the optimal conditions for the preparation of AC with enhanced properties. Despite its low specific surface area (25 m²/g), the prepared AC showed a higher adsorption capacity toward AY (5.71 mg/g) as compared with that of the commercial activated carbon (CC) (5.27 mg/g) which showed a higher specific surface area (825 m²/g). This could be due to the existence of pores and functional groups on the surface of AC, as evidenced by the analysis results of FTIR, DSC, and SEM. The adsorption process was found fast and fractal since it followed the kinetic model of the Brouers-Sotolongo fractal (BSf) (R² = 0.999), while the mathematical modeling of the adsorption isotherm of AY on the synthesized AC was stochastic since it followed the General Brouers-Sotolongo (GBS) (R² = 0.999).

Keywords: Activated carbon; Agave americana fibers; Alpacide yellow dye; Chemical activation; Fractal adsorption kinetic; Stochastic adsorption isotherm.