Since Yan's work, incorporation of some lanthanide elements, such as Eu and Nd, into MAPbI3 layer has been proven to be a powerful strategy on improving the permanence of the perovskite solar cells (PSCs). However, a comprehensive configuration has not been given for different lanthanide elements doping while the mechanism has not been clarified. Herein, the incorporation of various lanthanides ions (Ln3+ = Ce3+ , Eu3+ , Nd3+ , Sm3+ , or Yb3+ ) into perovskite films to largely enhance the performance of PSCs is presented. Arising from the enlarged grain size and crystallinity of perovskite film upon Ln3+ ions doping, the efficiency and stability of PSCs are significantly improved. Extraordinarily, PSCs with Ce3+ doping achieve the best performance, with a champion power conversion efficiency (PCE) of 21.67% in contrast to 18.50% for pristine PSCs, and outstanding long-term and UV irradiation stability. Such high performance of PSCs after Ce3+ doping originates from special Ce3+ /Ce4+ redox pair and the unique 4f-5d absorption in the UV region. Finally, the flexible PSCs with low-temperature preparation are explored. Considering the richer deposition of cerium element in the earth and lower price, the findings may provide new opportunities for developing low-cost, highly efficient, air/UV stable, and flexible PSCs.
Keywords: flexibility and large area; incorporating; lanthanide ions; perovskite solar cells; stabilities.
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