Electrically Driven Rotation and Nonreciprocal Motion of Microparticles in Nematic Liquid Crystals

Small. 2020 Oct;16(40):e2003352. doi: 10.1002/smll.202003352. Epub 2020 Sep 6.

Abstract

Dispersion of microparticles in nematic liquid crystals offers a novel means for controlling both their orientation and position through the combination of topology and external stimuli. Here, cuboidal and triangular prism shaped microparticles in parallel plate capacitor cells filled with a nematic liquid crystal are studied. Experimental observations are compared with numerical simulations to show that the optimal orientation of the particles is determined by their aspect rations, the relative separation gap of their containers and the applied voltage. It is observed that in systems that allow unrestricted particle rotation, the long axes of the particles are able to fully align themselves with the external electric field. However, when particle rotation is geometrically restricted, it is found that increasing the voltage past a critical value causes the short axis of the particle to realign with the electric field due to anchoring breaking. It is shown that symmetry of the particles then plays a key role in their dynamics following the removal of the electric field, allowing the triangular prisms to travel perpendicular to the applied electric field, whereas only rotation is possible for the cuboidal particles.

Keywords: liquid crystal dispersions; microparticles; nematic fluids; nonreciprocal motion; topological electrophoresis.

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