A New bis(rhodamine)-Based Colorimetric Chemosensor for Cu2

Inorg Chem Commun. 2020 Oct:120:108154. doi: 10.1016/j.inoche.2020.108154. Epub 2020 Jul 28.

Abstract

A novel sensor (RD) bearing rhodamine B and 4-tert-Butyl phenol unit have been designed and synthesized using microwave irradiation. The sensor allows selective detection of Cu2+ by forming absorptive complex and trigger the formation of highly colored ring-open spirolactam. The recognition ability of the sensor was investigated by absorbance, Job's plot, infrared (IR) and time dependent-density functional theory (TD-DFT) calculations.

Keywords: Absorbance; Colorimetric; Cu2+; Microwave; Rhodamine; Sensor.