Continuously growing interest in the controlled and tunable transport or separation of target molecules has attracted more attention recently. However, traditional "on-off" stimuli-responsive membranes are limited to nongradient feedback, which manifests as filtration efficiency that cannot be increased or decreased gradually along with the different stimuli conditions; indeed, only the transformation of on/off state is visible. Herein, we design and fabricate a series of robust salt-responsive SiO2@cellulose membranes (SRMs) by simply combining salt-responsive poly[3-(dimethyl(4-vinylbenzyl)ammonium)propyl sulfonate] (polyDVBAPS)-modified SiO2 nanoparticles and cellulose membranes under negative-pressure filtering. The antipolyelectrolyte effect induces stretch/shrinkage of polyDVBAPS chains inside the channels and facilities the directional aperture size and surface wettability variation, greatly enhancing the variability of interfacial transport and separation efficiency. Due to the linear salt-responsive feedback mechanism, the optimal SRMs achieve highly efficient target macromolecule separation (>75%) and rapid oil/saline separation (>97%) with a continuous gradient and adjustable permeability, instead of simply an "on-off" switch. The salt-responsive factors (SiO2-polyDVBAPS) could be reversibly separated or self-assembled to membrane substrates; thus, SRMs achieved unprecedented repeatability and reusability even after long-term cyclic testing, which exceeds those of currently reported membranes. Such SRMs possess simultaneously a superfast responsive time, a controllable gradient permeability, a high gating ratio, and an excellent reusability, making our strategy a potentially exciting approach for efficient osmotic transportation and target molecule separation in a more controllable manner.
Keywords: antipolyelectrolyte; gradient transport; macromolecules screening; oil/saline separation; polymer brush; salt-responsive membrane.