Perrhenate and Pertechnetate Complexes of U(IV), Np(IV), and Pu(IV) with Dimethyl Sulfoxide as an O-Donor Ligand

Grigory Andreev; Nina Budantseva; Marina Sokolova; Aleksander Fedoseev

doi:10.1021/acs.inorgchem.0c01036

Perrhenate and Pertechnetate Complexes of U(IV), Np(IV), and Pu(IV) with Dimethyl Sulfoxide as an O-Donor Ligand

Inorg Chem. 2020 Aug 17;59(16):11357-11365. doi: 10.1021/acs.inorgchem.0c01036. Epub 2020 Jul 31.

Authors

Grigory Andreev¹, Nina Budantseva¹, Marina Sokolova¹, Aleksander Fedoseev¹

Affiliation

¹ Institute of Physical Chemistry and Electrochemistry, 31 Leninsky pr., 119071, Moscow, Russia.

PMID: 32799473
DOI: 10.1021/acs.inorgchem.0c01036

Abstract

A series of new dimethyl-sulfoxide-containing pertechnetates and perrhenates of tetravalent U, Np, and Pu were synthesized and structurally characterized by the X-ray diffractometry. In all the synthesized compounds, the actinide atoms were coordinated by eight DMSO molecules with or without an extra XO₄^- anion in the coordination sphere. This resulted in the square antiprismatic or capped square antiprismatic coordination of An atoms. Three or four XO₄^- anions play the role of outer-sphere anions. The electron and IR spectra of the compounds correlated with their crystal structure.