Developing 3D-Printable Cathode Electrode for Monolithically Printed Microbial Fuel Cells (MFCs)

Molecules. 2020 Aug 10;25(16):3635. doi: 10.3390/molecules25163635.

Abstract

Microbial Fuel Cells (MFCs) employ microbial electroactive species to convert chemical energy stored in organic matter, into electricity. The properties of MFCs have made the technology attractive for bioenergy production. However, a challenge to the mass production of MFCs is the time-consuming assembly process, which could perhaps be overcome using additive manufacturing (AM) processes. AM or 3D-printing has played an increasingly important role in advancing MFC technology, by substituting essential structural components with 3D-printed parts. This was precisely the line of work in the EVOBLISS project, which investigated materials that can be extruded from the EVOBOT platform for a monolithically printed MFC. The development of such inexpensive, eco-friendly, printable electrode material is described below. The electrode in examination (PTFE_FREE_AC), is a cathode made of alginate and activated carbon, and was tested against an off-the-shelf sintered carbon (AC_BLOCK) and a widely used activated carbon electrode (PTFE_AC). The results showed that the MFCs using PTFE_FREE_AC cathodes performed better compared to the PTFE_AC or AC_BLOCK, producing maximum power levels of 286 μW, 98 μW and 85 μW, respectively. In conclusion, this experiment demonstrated the development of an air-dried, extrudable (3D-printed) electrode material successfully incorporated in an MFC system and acting as a cathode electrode.

Keywords: 3D-printing; EVOBOT; MFC; additive manufacturing; air-breathing cathode; alginate; electrode materials.

MeSH terms

  • Alginates / chemistry
  • Bioelectric Energy Sources* / economics
  • Carbon / chemistry
  • Electrochemical Techniques
  • Electrodes
  • Equipment Design
  • Printing, Three-Dimensional*

Substances

  • Alginates
  • Carbon