Applying ultrasonic fields to separate water contained in medium-gravity crude oil emulsions and determining crude oil adhesion coefficients

Ali Sadatshojaie; David A Wood; Seyyed Mohammad Jokar; Mohammad Reza Rahimpour

doi:10.1016/j.ultsonch.2020.105303

Applying ultrasonic fields to separate water contained in medium-gravity crude oil emulsions and determining crude oil adhesion coefficients

Ultrason Sonochem. 2021 Jan:70:105303. doi: 10.1016/j.ultsonch.2020.105303. Epub 2020 Aug 4.

Authors

Ali Sadatshojaie¹, David A Wood², Seyyed Mohammad Jokar³, Mohammad Reza Rahimpour⁴

Affiliations

¹ Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran. Electronic address: ali.sadatshojaie@gmail.com.
² DWA Energy Limited, Lincoln, United Kingdom. Electronic address: dw@dwasolutions.com.
³ Department of Chemical, Petroleum and Gas Engineering, Shiraz University of Technology, Shiraz, Iran. Electronic address: jokar@sutech.ac.ir.
⁴ Department of Chemical and Petroleum Engineering, Shiraz University, Shiraz, Iran. Electronic address: rahimpor@shirazu.ac.ir.

Abstract

Separating produced water is a key part of production processing for most crude oils. It is required for quality reasons, and to avoid unnecessary transportation costs and prevent pipework corrosion rates caused by soluble salts present in the water. A complicating factor is that water is often present in crude oil in the form of emulsions. Experiments were performed to evaluate the performance of ultrasonic fields in demulsifying crude oil emulsions using novel pipe-form equipment. A horn-type piezoelectric ultrasonic transducer with a frequency of 20 kHz and power ranging from 80 W to 1000 W was used for experimental purposes. The influences of the intensity of ultrasonic fields, ultrasonic irradiation time, and the initial water content of crude oils were evaluated to establish the rate of water segregation from oil. The experiments applied ultrasonic-field intensities of 0.25 W/cm³, 0.5 W/cm³, 0.75 W/cm³ and 1 W/cm³ to synthetic emulsions with 10%, 15%, 20%, and 25% of the water in crude oil. Crude oil demulsification occurred for each ultrasonic field intensity tested for all the samples tested. Function β involving adhesion coefficients was expressed in terms of wave-field intensity and initial concentration of water in each of the three crude oil samples tested. The experiments demonstrated that despite the absence of any chemical demulsifier involved, water separation caused by applying ultrasonic fields was effective and occurred rapidly. As the intensity of the ultrasonic field applied increased, the amount of water segregated from crude oil also increased. Subjected to constant field intensity, higher initial water cuts (up to 15% or so) in the crude oil samples and higher ultrasonic irradiation times, resulted in greater segregation of water from crude oil in percentage terms. However, in samples with initial water cuts of 20+% long irradiation times (~5 min), resulted in a decline in water separation compared to 2-min tests. Ultrasonic field treatments offer commercially-viable and environmentally-friendly alternatives to treatments using chemical demulsifiers as they reduce desalination requirements of wastewater.

Keywords: Adhesion coefficients; Crude oil dewatering, water-in-oil emulsion; Demulsification; Pipe-form ultrasonic field tester; Water plus salt separation.