Mg17Al12 phase in magnesium alloy waste facilitating the Ni2+ reduction in nickel plating wastewater

Abstract

A process for recycling Ni²⁺ in Ni-plating wastewater was investigated. This study employed Mg alloy flash waste to reduce the Ni²⁺ in the wastewater into metallic Ni. Fine second-phase Mg₁₇Al₁₂ in a network is the critical point for promoting the reduction reaction of Ni²⁺. The microstructures of the Mg alloy flash scrap and the die-cast Mg alloy scrap waste fulfilled the requirement. The Mg₁₇Al₁₂ is like a catalyst for the quick reduction of the Ni²⁺ ions into pure Ni metal. Contrarily, pure Mg (not containing Mg₁₇Al₁₂ particles) and gravity-cast AZ91D Mg alloy (having coarse Mg₁₇Al₁₂ particles) were not suitable for being used for the Ni²⁺ wastewater treatment. Based on the above results and discussion, using the Mg alloy flash scrap waste for treating the laboratory-made Ni²⁺-containing wastewater, the wastewater initially with ∼5600 ppm of Ni²⁺ ions could be reduced to ∼20 ppm in 2 h. When applying the Mg alloy flash scrap for the Ni plating wastewater from industry, the concentration of Ni²⁺ was able to be reduced from ∼16,670 ppm to ∼1434 ppm in 10 min for the wastewater at 90 °C.

Keywords: Galvanic corrosion; Magnesium alloy waste; Nickel recycling; Wastewater.