Degradation of benzene present in wastewater using hydrodynamic cavitation in combination with air

Pooja Thanekar; Parag R Gogate; Z Znak; Yu Sukhatskiy; R Mnykh

doi:10.1016/j.ultsonch.2020.105296

Degradation of benzene present in wastewater using hydrodynamic cavitation in combination with air

Ultrason Sonochem. 2021 Jan:70:105296. doi: 10.1016/j.ultsonch.2020.105296. Epub 2020 Jul 31.

Authors

Pooja Thanekar¹, Parag R Gogate², Z Znak³, Yu Sukhatskiy⁴, R Mnykh⁴

Affiliations

¹ Department of Chemical Engineering, Institute of Chemical Technology, Matunga, Mumbai 40019, India.
² Department of Chemical Engineering, Institute of Chemical Technology, Matunga, Mumbai 40019, India. Electronic address: pr.gogate@ictmumbai.edu.in.
³ Institute of Chemistry and Technical University, Lviv Polytechnic National University, Bandera Str. Lviv 79013, Ukraine. Electronic address: znak_zo@ukr.net.
⁴ Institute of Chemistry and Technical University, Lviv Polytechnic National University, Bandera Str. Lviv 79013, Ukraine.

Abstract

The degradation of benzene present in wastewater using hydrodynamic cavitation (HC) alone as well as in combination with air has been studied using nozzles as cavitating device of HC reactor. Initially, the energy efficiency of the HC reactor operated at different inlet pressures was determined using the calorimetric studies. Maximum energy efficiency of 53.4% was obtained at an inlet pressure of 3.9 bar. The treatment processes were compared under adiabatic as well as isothermal conditions and it was observed that under the adiabatic condition, the extent of degradation is higher as compared to isothermal condition. Studies related to the understanding the effect of inlet pressure (range of 1.8-3.9 bar) revealed that the maximum degradation as 98.9% was obtained at 2.4 bar pressure using the individual operation of HC under adiabatic conditions and in 70 min of treatment. The combination of HC with air was investigated at different air flow rates with best results for maximum degradation of benzene achieved at air flow rate of 60 mL/sec. A novel approach of using cavitation for a limited fraction of total treatment time was also demonstrated to be beneficial in terms of the extent of degradation as well as energy requirements and cost of operation. Based on the cavitational intensity, the resonant radius of aggregates of cavitation bubbles was also determined for distilled water as well as for aqueous solution of benzene. Overall, significant benefits of using HC combined with air have been demonstrated for degradation of benzene along with fundamental understanding into cavitation effects.

Keywords: Air; Benzene degradation; Energy efficiency; Hydrodynamic cavitation; Nozzles; Process intensification.