At the end of August 2019, in Warsaw, the sewage collection system of the Wastewater Treatment Plant malfunctioned. During the subsequent 12 days, over 3.6 million m3 of untreated sewage was introduced from the damaged collector directly into the Vistula River. It is one of the biggest known failures of its kind in the world so far. In this study we investigated to what extent the incident contributed to the increased discharge of anti-inflammatory drugs into the environment. The study covered the section from the point of discharge to the city of Toruń (ca. 170 km downstream). It was found that in the river waters downstream of the damaged collector, the concentrations of selected pharmaceuticals increased considerably in comparison with the waters upstream of the collector. The highest concentrations were observed for paracetamol (102.9 μg/L), ibuprofen (5.3 μg/L) and diclofenac (4.8 μg/L). We also measured to what extent and at what rate these pollutants were distributed along the river. The effects of the incident were observed in further parts of the river after 16 days. In the study we also detected elevated concentrations of ibuprofen and diclofenac in the bottom sediments collected 6 weeks after the failure. Measurements of the levels of pharmaceuticals in estuarial and marine waters in the vicinity of the mouth of the Vistula River indicate that the incident did not significantly increase the load of these pollutants in the waters of the southern Baltic Sea.
Keywords: Emerging pollutants; Pharmaceutical residues; River water; Sediment; WWTP failure; WWTP “Czajka”.
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