Amylose-lipid complex formation from extruded maize starch mixed with fatty acids

Carbohydr Polym. 2020 Oct 15:246:116555. doi: 10.1016/j.carbpol.2020.116555. Epub 2020 Jun 15.

Abstract

Functional modifications of starch, such as paste properties, retrogradation, water absorption indexes, solubility, and swelling capacity, are induced by the amylose-lipid complex. This research comprehends the study of functional properties of extruded maize starch mixed with fatty acids (stearic acid, oleic acid, and maize oil) and the formation of amylose-lipid complexes. Maize starch with lipids (5 or 10 %), moisture (35 %) was extruded (single screw). Starch granule was modified by extrusion, to a lesser extent at 10 % of lipids, especially stearic acid, which covers starch granule surface. Viscosity decreased meaningfully with stearic acid addition. DSC showed both starch gelatinization enthalpy and amylose-lipid complex enthalpy for stearic or oleic acid, but it was just the first enthalpy for maize oil. X-ray diffraction showed orthorhombic crystals with or without the presence of lipids. Our results indicated that stearic acid yielded the highest amount of amylose-lipid complexes.

Keywords: Amylose-lipid complex; Extrusion; Starch; Type V starch.

MeSH terms

  • Amylose / chemistry*
  • Calorimetry, Differential Scanning
  • Crystallization
  • Hot Temperature
  • Lipids / chemistry*
  • Oleic Acid / chemistry*
  • Plant Extracts / chemistry*
  • Solubility
  • Stearic Acids / chemistry*
  • Viscosity
  • Water / chemistry
  • X-Ray Diffraction
  • Zea mays / chemistry*

Substances

  • Lipids
  • Plant Extracts
  • Stearic Acids
  • Water
  • Oleic Acid
  • stearic acid
  • Amylose