Effect of Porosity on Functional Properties of Lead-Free Piezoelectric BaZr0.15Ti0.85O3 Porous Ceramics

Materials (Basel). 2020 Jul 26;13(15):3324. doi: 10.3390/ma13153324.

Abstract

The present paper reports the dependence of dielectric, ferroelectric and piezoelectric properties on the porosity level in BaZr0.15Ti0.85O3 ceramics with porosity from 5% to 21%. Microporosity with 0-3 connectivity has been produced using PMMA microspheres as a sacrificial template. The functional properties (dielectric, ferroelectric and piezoelectric effect) are mostly affected by the "dilution effect": permittivity decreases by 40% when porosity increases by 21%, and Pmax decreases from 13 to 5 µC/cm2 while the Prem is in the range of (2-8) µC/cm2. However, the reduction of the zero-field permittivity and hysteretic behaviour of ε(E) while the tunability level is still high makes from porous ceramics interesting materials for tunability application.

Keywords: DC tunability; dielectric properties; piezoelectric coefficient; porous ceramics.