The evolution of modern technology and industrial processes has been accompanied by an increase in the utilization of chemicals to derive new products. Water bodies are frequently contaminated by the presence of conventional pollutants such as dyes and heavy metals, as well as microorganisms that are responsible for various diseases. A sharp rise has also been observed in the presence of new compounds heretofore excluded from the design and evaluation of wastewater treatment processes, categorized as "emerging pollutants". While some are harmless, certain emerging pollutants possess the ability to cause debilitating effects on a wide spectrum of living organisms. Photocatalytic degradation has emerged as an increasingly popular solution to the problem of water pollution due to its effectiveness and versatility. The primary objective of this study is to thoroughly scrutinize recent applications of titanium dioxide and its modified forms as photocatalytic materials in the removal and control of several classes of water pollutants as reported in literature. Different structural modifications are used to enhance the performance of the photocatalyst such as doping and formation of composites. The principles of these modifications have been scrutinized and evaluated in this review in order to present their advantages and drawbacks. The mechanisms involved in the removal of different pollutants through photocatalysis performed by TiO2 have been highlighted. The factors affecting the mechanism of photocatalysis and those affecting the performance of different TiO2-based photocatalysts have also been thoroughly discussed, thereby presenting a comprehensive view of all aspects involved in the application of TiO2 to remediate and control water pollution.
Keywords: Emerging pollutants; Immobilization; Nanostructures; Organic pollutants; Photocatalysis; TiO2.
Copyright © 2020 Elsevier Ltd. All rights reserved.