The photo-driven oxidation of organic molecules into corresponding high-value-added products has become a promising method in chemical synthesis. This strategy can drive thermodynamically non-spontaneous reactions and achieve challenging thermocatalytic processes under ambient conditions. Reactive oxygen species (ROS) are not only significant intermediates for producing target products via photoinduced oxidation reactions but also contribute to the creation of sustainable chemical processes. Here, the latest advances in heterogeneous photo-driven oxidation reactions involving ROS are summarized. The major types of ROS and their generation are introduced, and the behaviors of various ROS involved in photo-driven processes are reviewed in terms of the formation of different bonds. Emphasis is placed on unraveling the reaction mechanisms of ROS and establishing strategies for their regulation, and the remaining challenges and perspectives are summarized and analyzed. This Review is expected to provide an in-depth understanding of the mechanisms of ROS involved in photo-driven oxidation processes as an important foundation for the design of efficient catalysts. Clarifying the role of ROS in oxidation reactions has important scientific significance for improving the atomic and energy efficiency of reactions in practical applications.
Keywords: organic synthesis; photocatalysis; reaction mechanism; reactive oxygen species; selective oxidation.
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