Physicochemical and functional properties of native and modified agave fructans by acylation

Abstract

Native agave fructans were modified by an acylation reaction with lauric acid. Native and modified fructans were characterized using NMR, FTIR and various physicochemical and functional properties at different pHs were evaluated. NMR and FTIR spectra demonstrated the incorporation of lauric acid in the molecular structure of fructans. Modified agave fructans exhibited a color, moisture and water activity similar to native fructans, but properties such as solubility, swelling capacity, emulsifying activity and foam capacity were significantly modified by the acylation reaction mainly when the samples were analyzed at different pHs. The thermogram of the acylated fructans evidenced significant changes in thermal properties when compared with native fructans and acylated fructans were able to form micellar aggregates. In general, modified fructans showed improved functional properties in comparison with native fructans representing an important opportunity to improve the functionality of the foods in which it is incorporated.

Keywords: Acylation; Deuterated water (PubChem CID: 24602); Deutero chloroform (PubChem CID: 71583); Esterification; Fructans; Hexane (PubChem CID: 8058); Lauric acid (PubChem CID: 3893); Lauroyl chloride (PubChem CID: 8166); Modified carbohydrates; Nitrogen gas (PubChem CID: 947); Phosphate buffered saline (PubChem CID: 24978514); Sodium hydroxide (PubChem CID: 14798); Surface tension; d-Fructose (PubChem CID: 5984).