Improving the regulatory health risk assessment of mercury-contaminated sites

Abstract

An alternative risk assessment strategy for mercury (Hg)-contaminated sites is proposed with bioaccessible fractions and soil Hg vapor (SHgV) concentrations. The new strategy avoids the conservatism of assessment rely on soil total Hg (THg) content and inaccuracy caused by predicted SHgV concentration. The exposure risk to Hg-contaminated soil associated with historical mining activities in Guizhou, China, was evaluated using the proposed strategy. The experimental results revealed that the average bioaccessibility in gastric, intestinal and lung phases was 10.39 % (2.09 % ∼ 35.28 %), 1.28 % (0.23 % ∼ 4.3 %), and 11.27 % (5.04 % ∼ 20.71 %), respectively. Via the proposed strategy, the Hg risk for the oral ingestion pathway, represented as the hazard quotient (HQ), decreased from 1.57 to an acceptable level of 0.19 (<1). The risk of SHgV inhalation sharply decreased from 1168 to 0.35 while the soil PM₁₀ inhalation pathway did not exhibit significant variations. The dominant exposure pathways turned to oral intake and inhalation of SHgV by the strategy. The results indicated that the proposed assessment strategy can greatly improve the understanding of the exposure risk level at Hg-contaminated sites and provide a reasonable decision basis for decision makers.

Keywords: Bioaccessibility; Exposure risk; Mercury; Risk assessment; Soil vapor.