Self-propelled torus colloids

J Chem Phys. 2020 Jul 7;153(1):014902. doi: 10.1063/5.0012265.

Abstract

Suspensions of chemically powered self-propelled colloidal particles are examples of active matter systems with interesting properties. While simple spherical Janus particles are often studied, it is known that geometry is important and recent experiments have shown that chemically active torus-shaped colloids behave differently from spherical colloids. In this paper, coarse-grained microscopic simulations of the dynamics of self-diffusiophoretic torus colloids are carried out in bulk solution in order to study how torus geometric factors influence their active motion. The concentration and velocity fields are key ingredients in self-diffusiophoretic propulsion, and the forms that these fields take in the colloid vicinity are shown to be strong functions of torus geometric parameters such as the torus hole size and thickness of the torus tube. This work utilizes a method where self-diffusiophoretic torus colloids with various geometric and dynamical characteristics can be built and studied in fluid media that include chemical reactions and fluid flows. The model can be used to investigate the collective properties of these colloids and their dynamics in confined systems, topics that are of general importance for applications that use colloidal motors with complex geometries.