New Variants of Nitroxide Mediated Polymerization

Gérard Audran; Elena G Bagryanskaya; Sylvain R A Marque; Pavel Postnikov

doi:10.3390/polym12071481

New Variants of Nitroxide Mediated Polymerization

Polymers (Basel). 2020 Jul 2;12(7):1481. doi: 10.3390/polym12071481.

Authors

Gérard Audran¹, Elena G Bagryanskaya^{2

3}, Sylvain R A Marque¹, Pavel Postnikov^{4

5}

Affiliations

¹ Aix Marseille Univ, CNRS, ICR, UMR 7273, Case 551, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France.
² N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry Siberian Branch of Russian Academy of Sciences, Pr. Lavrentjeva 9, Novosibirsk 630090, Russia.
³ Novosibirsk State University, Pirogova str. 2, Novosibirsk 630090, Russia.
⁴ Department of Solid State Engineering, University of Chemistry and Technology, 16628 Prague, Czech Republic.
⁵ Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Lenin Ave, 30, Tomsk, Tomsk Oblast 634050, Russia.

Abstract

Nitroxide-mediated polymerization is now a mature technique, at 35 years of age. During this time, several variants have been developed: electron spin capture polymerization (ESCP), photoNMP (NMP2), chemically initiated NMP (CI-NMP), spin label NMP (SL-NMP), and plasmon-initiated NMP (PI-NMP). This mini-review is devoted to the features and applications of these variants.

Keywords: CI-NMP; ESCP; NMP2; PI-NMP; SLNMP; nitroxide mediated polymerization.

Publication types

Review

Grants and funding

14.W03.31.0034/Ministry of Education and Science of the Russian Federation